first Redis is very flexible, so you can key names and data structure to use for users, try not approach this thinking in structured way like mySQL.
an integer to keep track of the user id.
global:index:users
storing user password as a string
user:<id>:password
storing user information in a hash
user:<id>
name=>username
email=>user email
some other key=>some other data
get userid by password, since we don't want to look entire user:<id>
to get who's password is it.
user:<passwordHash>:id
of
user:<name>:id