What is your clock mode ?
Looking at the datasheet, section Clock Mode or p176, configuration bits, at the CONFIG register, you may choose between different clock mode.
http://ww1.microchip.com/downloads/en/DeviceDoc/41262A.pdf
You may be using the INTOSC mode (CONFIG.FOSC2-0=101).
"CLKOUT function on RA4/AN3/T1G/OSC2/CLKOUT pin, I/O function on RA5/T1CKI/OSC1/CLKIN".
You could use the INTOSCIO instead (CONFIG.FOSC2-0=100)
"I/O function on RA4/AN3/T1G/OSC2/CLKOUT pin, I/O function on RA5/T1CKI/OSC1/CLKIN"
Same thing for RC -> RCIO mode (CONFIG.FOSC2-0=111 -> CONFIG.FOSC2-0=110).
It is likely that the CLKOUT mode has the right of way over the A/D mode. Try to change the clock mode !
Bye,