this is from this answer which is a duplicate of this one. You check in your app's entry constructor for whether or not the app is already running.
static void Main()
{
Process currentProcess = Process.GetCurrentProcess();
var runningProcess = (from process in Process.GetProcesses()
where
process.Id != currentProcess.Id &&
process.ProcessName.Equals(
currentProcess.ProcessName,
StringComparison.Ordinal)
select process).FirstOrDefault();
if (runningProcess != null)
{
ShowWindow(runningProcess.MainWindowHandle, SW_SHOWMAXIMIZED);
return;
}
}