You can try this:
$nc = gwmi Win32_NetworkConnection
if (( $nc | select -expa remotename ) -contains '\\poooh.fooo.boo.com\MyFolder' )
{
$u = $nc | ? { $_.remotename -eq '\\poooh.fooo.boo.com\MyFolder' } | select -expa localname
$netobj=New-Object -ComObject WScript.Network
$netobj.RemoveNetworkDrive($u)
}
The remove may fail if connection have files opened.