Hidden fields will be the silver bullets here.
step1. add a asp hiddenfield to your page lets say hf1 is its id.
step2. add a clientclick event to your save button
step3.in the client clickevent get all personal skill and make them into a single string using comma or '|'
step4. set the hf1 value to the string generated by step3 and then post it.
step 5.On the server side get the value of the hf1 which will be the same string generated in 3rd step.
step6. deserialize it and //do any thing you want.
hope this help