Have another table with fields userid, isset - ( with default value of 1 for all users)
If user clicks the remove profile pic( wishes to have the default pic) , change the value in isset to 0 for the respective user.
Check this table everytime before fetching the latest image from the profile pics table.
Alternatively you can have the isset field in the profile pics table itself. This would require you to change the isset value of every occurrence of the user's profile pic if he wishes to have the default pic.