If quoting as "Value"
doesn't work, then you are using a dialect 1 database (or you have connected with dialect 1). Dialect 1 doesn't support quoted identifiers, it has been deprecated since before Firebird existed (when it was still Interbase 6 beta in 1999/2000).
If this is a new database then restart with a dialect 3 database. If this is an existing database, then you really should consider migrating it to dialect 3. See "Migrating databases to dialect 3" in the Interbase 6 Getting started manual (available from http://www.firebirdsql.org/en/reference-manuals/ it is in the Full Set linked at the end of the page).