To access XML
element attributes you must use appropriate XPath
syntax.
declare @BillingAddresses xml
set @BillingAddresses=convert(xml,N'
<BillingAddresses>
<BillingAddress Address1="P.O. Box 2162" City="Huntington Beach"/>
<BillingAddress Address1="12933 Monarch" City="Aliso Viejo"/>
<BillingAddress Address1="6666 Von Karman Ave" City="Irvine"/>
</BillingAddresses>')
SELECT
Addr.Col.value('@Address1', 'varchar(100)'),
Addr.Col.value('@City', 'varchar(100)')
FROM @BillingAddresses.nodes('/BillingAddresses/BillingAddress') Addr(Col)