That third column is a factor variable; you might want to check your code to make sure that is what you actually want. Anyway, you can add the level manually if you're sure it's what you want to do. Here's an example of adding a level on iris
R>iris$Species[5] <- "hahah"
Warning message:
In `[<-.factor`(`*tmp*`, 5, value = c(1L, 1L, 1L, 1L, NA, 1L, 1L, :
invalid factor level, NA generated
R>levels(iris$Species) <- c(levels(iris$Species), "hahah")
R>iris$Species[5] <- "hahah"
R>iris[5,]
Sepal.Length Sepal.Width Petal.Length Petal.Width Species
5 5 3.6 1.4 0.2 hahah