Are you trying to add a checkbox item that does not have a database field behind it? I have this on one of my forms.
In addition to setting the Properties to "Checkbox" you need to set the DataBinding -> ValueType to "Boolean". The DataBinding->FieldName can be left blank.
To access the values or change their defaults you can use the DataController like this:
View.DataController.Values[i, CheckBoxFieldIndex] := true;
In addition you need to set
DataController.DataModeController.SmartRefresh := true;
To set that option you will also need a KeyField defined for the Controller (DataController.KeyFieldNames)
Setting the SmartRefresh to true will prevent the grid from trying to get an updated value from the underlying dataset. You need to prevent the refresh or the value for the non-bound column will be set back to Null. This comes with some restriction on how you update your dataset. Any changes made to the data in code will not be reflected by the grid unless you explicitly refresh the grid.