Use convert
from the ImageMagick tools:
convert multilayer.xcf output.png
The result will be a separate PNG for each layer:
output-0.png
output-1.png
output-2.png
[…]
And: don't use JPG if you continue to print it on T-Shirts… JPG is lossy and doesn't support alpha-channels, which is important for most T-Shirt prints.