You can use NSDateComponents
for this task. Add one day (tomorrow) and set the hour and minute appropriately.
Example:
unsigned unitFlags = NSYearCalendarUnit | NSMonthCalendarUnit | NSDayCalendarUnit | NSHourCalendarUnit | NSMinuteCalendarUnit;
NSCalendar *calendar = [NSCalendar currentCalendar];
NSDateComponents *components = [calendar components:unitFlags fromDate:[NSDate date]];
components.day += 1;
components.hour = 14; // replace this with the value from your picker
components.minute = 30; // replace this with the value from your picker
NSDate *alertDate = [calendar dateFromComponents:components];