For any scrollPos
over 200 your first condition will fire, and therefore none of the tests for higher numbers will ever fire.
You need to change the order, putting the test for the highest number first:
if (scrollPos>3604){
$('.contact-btn').css("border-bottom", "5px solid #25bdad");
}
else if (scrollPos>1995){
$('.brands-btn').css("border-bottom", "5px solid #25bdad");
}
else if (scrollPos>1415){
$('.difference-btn').css("border-bottom", "5px solid #25bdad");
}
else if (scrollPos>690){
$('.who-btn').css("border-bottom", "5px solid #25bdad");
}
else if (scrollPos>200){
$( ".second-nav" ).slideDown();
}
else {
$( ".second-nav" ).slideUp();
}