I'd try using the Aggregation framework http://docs.mongodb.org/manual/aggregation/ .
Using your schema this should work:
db.user.aggregate([{$match:{"userName":"ztolley"}},{$unwind:"$data.temperature"},{$sort:{"data.temperature.timestamp":-1}},{$limit:10}, {$project:{"data.temperature":1, _id:0}}])
It returns the temperature readings for that user, in reverse sorted order by timestamp, limited to 10.