The term natural
refers, as you thought, to what is native on the hardware. Although it's not specified explicitly in a glossary, you can make it out from other uses of the word natural
in the spec:
The native size types (native int, native unsigned int, and &) are always naturally aligned (4 bytes or 8 bytes, depending on the architecture).
or
autochar indicates a platform-specific representation that is “natural” for the underlying platform