it's very simple
you just have to use "." insted of "+"
$From = $Date . 'T' . $Time . ':00'
Edit:
include 'Db.php';
$dateFrom = '2014-05-02' . 'T' . '09:00' . ':00';
$dateTo = '2014-05-02' . 'T' . '14:00' . ':00';
$con = DbConnect();
$sql = "insert into calendar(ContactName, DateFrom, DateTo, ContactPhone) values ('User', '".$dateFrom."', '".$dateTo."', '1234567' )";
if(mysqli_query($con,$sql)){
print(json_encode(mysqli_affected_rows($con)));
mysqli_close($con);
}