To answer the second half of your questions first, that expression can be described as follows:
The language La is comprised of the set of words w, where the length of w is a multiple of 3 and w starts with aa.
The vertical bar introduces the conditions that w must meet to be included in the set.
The bars on either side of the second w indicate length.
Then looking at the answer, you have aa, because that's what the word must start with, followed by one other letter (a, b or c), giving you a 3 letter word that's a match.
After that, any other words would need to have an additional 3 letters, each of which can be a, b or c. So the asterisk (*) indicates that this can occur 0 or more times, and the brackets [] just denote which part of the expression the asterisk applies to.