You might be looking for "fork," which will make it easy to use the specific item.
- http://docs.python.org/release/2.4/lib/os-process.html
- http://en.wikipedia.org/wiki/Fork_%28operating_system%29#Example_in_Python
Your for loop will need to look a little different, though -- you want to break out as soon as fork returns zero.
import os
L = ["a", "b", "c"]
for item in L:
pid = os.fork()
if pid == 0: break
else: print "Forked:", pid
if pid != 0: print "Main Execution, Ends"
else: print "Execution:", item