If you use device replay mode (as described in this answer) and send a vbCRLF
your application will be able to see the enter key.
Setting.WebPackage("ReplayType") = 2 ''# Changes to device mode
Browser("Enter").Page("Enter").WebEdit("WebEdit").Set "a" & vbCRLF
This works (on IE) for the following sample page:
<!DOCTYPE html>
<html>
<head>
<title>Enter</title>
<script>
function okd() {
if (event.keyCode == 13)
alert("Got enter");
}
</script>
</head>
<body>
<textarea onkeydown="okd()"></textarea>
</body>