You can only use a modifier key in conjunction with another key. You cannot use a modifier key by itself. This is the same in every language that I have come across. The modifier key modifies the action of one or more further keys.
Even if it were possible, it would be unadvisable because if it were used on its own, then you would not be able to use that modifier key with any other key combinations as it would be swallowed up by the first action as soon as it was pressed.