If I understand your question right, you want to get the value of every option that is in the select under Available?
In the given example this select has the id "columnListms2side__sx", so that you can get the values of its options with
var multipleValues = [];
$("#columnListms2side__sx option").each(function()
{
multipleValues.push($(this).val())
});
here's the updated fiddle: http://jsfiddle.net/VFskn/3/
!important notes though: its not a good idea to mess with it, other then the functions provided by the plugin. And I'm not sure how safe it is too assume that this select will allways get this id (e.g. if you have multiple of them in one page). It might be smarter to, build a more generic select. (the plugin seems to create a div container after the select it replaces, you want to get the first select in there)
EDIT: this would be more generic, but less efficient:
$("#columnList").next().find("select").filter(":first").children().each(function(){...}
updated fiddle: http://jsfiddle.net/VFskn/4/