The library "ArduinoIO" does not support SPI. That library is just a serial port listener, and every matlab/arduino instruction send a code by serial, that is readed in the sketch on the arduino, translated in the corresponding arduino's instruction, and then executed.
You can create your own block that send some your-choise-spi-command, you'll also have to edit the arduino's sketch to execure the corrisponding SPI command. But you'll have to understand how the library works, change it's code, and so on.
It is way more faster (in execution speed, as serial comunication really is slow, and coding time) to code a "specialized" arduino sketch, that send back to Serial just the value you need, and then read serial and to pc-side computation.