I managed to stumble across the answer to recently.
Basically the app could not locate the XML file in the Resource bundle because it wasn't there.
To add the XML to the resource bundle open up the solution in Xcode and click the top level of the solution in the solution explorer on the left hand side. Along the top there is now listed General, Capabilities etc. Go to Build Phases > Copy Bundle Resources > + > Locate the XML file that you have already added to the solution.
This should resolve the problem of not stating that the XML file URL is null.