Here's a bit of review of where you went wrong:
def x():
name = requestString("name")
usersName = list(name)
ascii = [orc(c) for c in usersName] # here's the list
for name in name:
print name, "=", ascii # and you're printing it here everytime
You could fix more pythonically like this:
def x():
name = requestString("name")
# usersName = list(name) # no need for this line, you can iterate over the string
ascii = [orc(c) for c in name] #so this is just name
for i, c in enumerate(name): # use c for your character var name,
print c, "=", ascii[i] # and enumerate provides the index
Since you're not returning anything, creating a list is unnecessary, you might as well provide the ord(c) on the fly:
def print_ords_of_word(name):
for c in name:
print c, '=', ord(c)