If you want to bind to the first Sigma Value, as suggested by the parameters[0] binding, best way is to add a property to your Norma class:
public class Norma
{
public decimal FirstSigma{get{return Parameters[0].Sigma;}} //add setter if needed
....
and bind to that:
textBox2.DataBindings.Add("Text", normBindingSource, "FirstSigma");
If you want to have a separate binding to the parameter list, a separate bindingsource should be created for the list
textBox2.DataBindings.Add("Text", aBindingSourceToParametersList, "Sigma");