I just built a sample app with my code to load a webview. I call a specific page in my form submission and it works to login to the web service. I am posting the code here:
NSString *username = @"abc";
NSString *password = @"abc";
NSString *postString = [NSString stringWithFormat:@"username=%@&password=%@",username, password];
NSLog(@"%@", postString);
NSData *postData = [postString dataUsingEncoding:NSUTF8StringEncoding allowLossyConversion:YES];
NSMutableURLRequest *request = [[NSMutableURLRequest alloc] init];
[request setURL:[NSURL URLWithString:@"http://www.someurl.com/loginscript"]];
[request setHTTPMethod:@"POST"];
[request setHTTPBody:postData];
[webView loadRequest:request];
Maybe this code will help you.