You have a multidimensional set of data, instead of $b["name"] What you want is:
$b["response"]["players"][0]["name"]
This is the json objects structure from that URL
{
"response": {
"success": 1,
"current_time": 1369778504,
"players": {
"0": {
"steamid": "76561198037411448",
"success": 1,
"backpack_value": 185.86,
"backpack_update": 1369543543,
"name": "Paranoid Android",
"stats_tf_reputation": 1,
"notifications": 0
}
}
}
}
If you need iteration, will have to loop through $b["response"]["players"]