I had the same problem - if you follow the instructions listed (ie installing devkit and following their directions [they don't actually tell you to use rubyinstaller]), you'll be fine. Also make sure that during the init phase of the Devkit instructions that it doesn't miss any of your ruby installations.
A note though, it seems that pik can't specify the x64 version of 2.0.0, so you may run into problems if that's the case. In the end I had to use the rubyinstaller for the x64 version of ruby, and then ran the x64 version of the devkit.
Hope this helps.