Check this ...
its not 02
its O2
in your code , it may be the error
HttpWebRequest httpWReq =
(HttpWebRequest)WebRequest.Create("http://api.amazon.com/auth/**02**/token");
Try this
HttpWebRequest httpWReq =
(HttpWebRequest)WebRequest.Create("https://api.amazon.com/auth/o2/token");
Thank you ...