Unfortunately, as per the documentation, you can't get a BlobInfo object for GCS files.
Note: Once you obtain a blobKey for the GCS object, you can pass it around, serialize it, and otherwise use it interchangeably anywhere you can use a blobKey for objects stored in Blobstore. This allows for usage where an app stores some data in blobstore and some in GCS, but treats the data otherwise identically by the rest of the app. (However, BlobInfo objects are currently not available for GCS objects.)