query_group is the part of WLM(workload management) configuration which enables you to manage how to run queries through queues on the Redshift cluster. To use query_group, you have to set up your own queue with query_group name(Label) through the AWS console([Amazon Redshift] -> [Parameter Groups] -> Select parameter group -> [WLM]) or cli in advance.
Here is an example which is snipped from the Redshift doc.
set query_group to 'Monday';
select * from category limit 1;
...
reset query_group
You have to set the query_group before starting the query which you want to assign to the specific queue, and reset the query_group after finishing.
You can track the queries of query_group as following. 'label' is the name of query_group.
select query, pid, substring, elapsed, label
from svl_qlog where label ='Monday'
order by query;
query | pid | substring | elapsed | label
------+------+------------------------------------+-----------+--------
789 | 6084 | select * from category limit 1; | 65468 | Monday
790 | 6084 | select query, trim(label) from ... | 1260327 | Monday
791 | 6084 | select * from svl_qlog where .. | 2293547 | Monday
792 | 6084 | select count(*) from bigsales; | 108235617 | Monday
...
This document is good to understand how WLM works and use it.
This link is about query_group.