There is no exact way to capture as a vector. Because of the capture program, not knowing of any geometry shapes.
Although, you can capture a raster image and convert it to a vector. There are numerous tools out there, that will allow you to do this conversion. Then you will have to do a little bit of tweaking. But in reality you cannot take a capture as a vector, or convert it and have it be "pixel-perfect".
Hope this helps!
Zachary