Albe's answer is good but it has some bad coding practices.
Following the same steps:
Import Tkinter as tk
top = tk.TK()
Define your function here and make it work for any button, not hard coded to the specific button you might use.
def toggle(button: tk.Button):
if button.config('relief')[-1] == 'sunken':
button.config(relief="raised")
else:
button.config(relief="sunken")
Then create and pack all the toggle buttons you want.
toggleButton = tk.Button(text="Toggle", width=12, relief="sunken",
command =lambda:toggle(toggleButton))
toggleButton.pack(pady=5)
top.mainloop()
This is better for two reasons. Creating the button object twice is redundant and will lead to buggy code. Hard coding the button to a specific toggle function is unscalable. This solution makes the code reusable and simple to add to. For example, replace that last block with:
for _ in range(4):
b = tk.Button(text="Toggle", width=12, relief="sunken")
b['command']= lambda a=b:toggle(a)
b.pack(pady=5)
And now you get 4 toggling buttons without any additional functions or copy/paste