You cannot do it in a single operation, but you can apply the sort descriptor to the result of the uniquing operation:
NSArray *uniqueArray = [mYearsArray valueForKeyPath:@"@distinctUnionOfObjects.self"];
NSArray *sortedUniqueArray = [uniqueArray sortedArrayUsingDescriptors:sortDescriptors];
mYearsArray = [sortedUniqueArray mutableCopy];