Why this Error occurs because you have set the URL wrong. You are setting url like that;
/Users/akrama2/Library/Application%20Support/iPhone%20Simulator/6.1/Applications/59356D13-C021-431F-A5D2-B8CD16E2B301/Documents/Application_Report.pdf
Where as UIDocumentationController task URL as:
file://localhost/Users/akrama2/Library/Application%20Support/iPhone%20Simulator/6.1/Applications/59356D13-C021-431F-A5D2-B8CD16E2B301/Documents/Application_Report.pdf
This minor mistake will made you mad ;)